We report here, for the first time, synthesis of anchored Pd complexes in mesoporous supports such as MCM-41 and MCM-48 as true heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols to give excellent ...

SBA-15 mesoporous silica has been functionalized with azidopropyl groups through both one-pot co-condensation and post-synthetic grafting. For both these methodologies, azidopropyltriethoxysilane was used to introduce the ...

Efficient Mizoroki–Heck couplings were obtained using a very easily synthesizable palladium(II) complex of hemilabile N–O ligand (picolinate), with high turnover frequencies up to >10,000 h−1, in just 15 min, with high ...

The technique known as ‘ossification’ has emerged as one of the most promising approaches for immobilisation of metal complexes, generating highly selective, stable and recyclable heterogeneous counterparts of homogeneous ...

Palladium complex [Pd(pyca)(PPh3)(OTs)] has been immobilized on solid matrices having ordered framework and high surface area as zeolite NaY (surface area ∼ 700 m2 g−1), using phosphotungstic acid [H3PW12O40, xH2O] as the ...