Browsing Department of Chemistry by Author "Sivasubramanian, S.C."

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Dioxygen binding and activation by a highly reactive Cr(II) compound containing S,N-donors derived from o-aminothiophenol

Sivasubramanian, S.C. (Taylor & Francis, 2012-08-07)

We report the synthesis, characterization, and reactivity of a Cr(II) complex, [Cr(H2O)(LISQ)2] (1) [(LISQ)1− is o-iminothionebenzosemiquinonate(1−) π-radical], that is highly stable in solid state in the presence of air ...
Imidazolium ionic liquid-tagged palladium complex: an efficient catalyst for the Heck and Suzuki reactions in aqueous media

Kumar, Anil; Sivasubramanian, S.C.; Khungar, Bharti (RSC, 2014)

An air stable, water soluble, and efficient ionic liquid-tagged Schiff base palladium complex was prepared. The synthesized complex was well characterized by NMR, mass spectrometry, FT-IR, UV-visible spectroscopy and powder ...
Imidazolium ionic liquid-tagged palladium complex: an efficient catalyst for the Heck and Suzuki reactions in aqueous media

Khungar, Bharti; Kumar, Anil; Sivasubramanian, S.C. (RSC, 2014)

An air stable, water soluble, and efficient ionic liquid-tagged Schiff base palladium complex was prepared. The synthesized complex was well characterized by NMR, mass spectrometry, FT-IR, UV-visible spectroscopy and powder ...
Magnetic resonance lineshapes in powdered and amorphous systems

Sivasubramanian, S.C. (IAS, 1986-04)

A survey is made of the theory and applications ofEPR andNMR absorption lineshapes observed in powdered and amorphous materials. The ‘spin Hamiltonian’ and ‘resonance condition’ formalisms are reviewed, andepr andnmr ...
A paramagnetic octahedral trans-dihydroxy chromium(IV) complex with dianionic tetradentate Schiff base salophen and crystal structure of its trans-diisothiocyanato analog

Sivasubramanian, S.C. (Taylor & Francis, 2012-09-06)

A paramagnetic octahedral trans-dihydroxychromium(IV) complex, [Cr(OH)2(salophen)] (1) (H2salophen = N,N′-bis(salicylidene)-1,2-phenylenediamine), has been synthesized and characterized by elemental analysis, magnetic ...
Synthesis and characterization of two stable paramagnetic octahedral chromium(IV) complexes with dianionic tridentate SNO donor ligands and of a chromium(III) complex with a ONO donor ligand

Sivasubramanian, S.C. (Elsiever, 2008-04-01)

Two novel paramagnetic octahedral chromium(IV) complexes with dianionic tridentate SNO donor ligands containing extended π-system have been synthesized while only a paramagnetic octahedral chromium(III) complex is obtained ...
X-ray diffraction, electron paramagnetic resonance, and electron spin echo modulation studies of the lead oxide-lead chloride-cupric chloride ternary glass system

Sivasubramanian, S.C. (ACS, 1991-08-01)

X-ray diffraction, EPR, and ESEM studies are reported for a novel ternary glass 43PbO-56PbCl2-1 CuCl2. The X-ray PDF data lead to a structural model in which octahedral building units of Cu04Cl2 are predominant. EPR spectra ...
X-ray diffraction, electron paramagnetic resonance, and electron spin echo modulation studies of the lead oxide-lead chloride-cupric chloride ternary glass system

Sivasubramanian, S.C. (ACS, 1991-08-01)

X-ray diffraction, EPR, and ESEM studies are reported for a novel ternary glass 43PbO-56PbCl2-1 CuCl2. The X-ray PDF data lead to a structural model in which octahedral building units of Cu04Cl2 are predominant. EPR spectra ...

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