Kinetics of Gas Phase Ion-Ion Recombination in NO++X- ->NO+X for X being Chlorine, Bromine and Iodine

Burdett, Hayhurst, Allan N. Nigel A.

dc.contributor.author	Burdett, Hayhurst, Allan N. Nigel A.
dc.date.accessioned	2025-11-19T13:03:01Z
dc.date.available	2025-11-19T13:03:01Z
dc.date.issued	1978
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20118
dc.description.abstract	The rate coefficient for the gas phase recombination of N0+ with halide ions X- in NO++X-->NO+X has been measured in flames of C2H2 + O2 + N2 over the temperature range 2200 to 2650 K. Chlorine, bromine and iodine have been used as X. All At values are in the range 0.8-2.lx 10~8 ion -1 cm3 s-1, corresponding to cross-sections (tto2) of ~10-17 m2. For each halogen, ki has a negative temperature coefficient. Also at any one temperature, kt is largest for X being chlorine and smallest for iodine. In general, these measurements are in agreement with Olson’s “ absorbing sphere ” model for ion-ion recombination.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (1)	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.subject	Chemistry	en_US
dc.subject	Kinetics	en_US
dc.subject	Chlorine	en_US
dc.title	Kinetics of Gas Phase Ion-Ion Recombination in NO++X- ->NO+X for X being Chlorine, Bromine and Iodine	en_US
dc.type	Article	en_US