Thermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volume

Oates, W. Alan; Flanagan, Ted B

dc.contributor.author	Oates, W. Alan
dc.contributor.author	Flanagan, Ted B
dc.date.accessioned	2025-11-21T05:43:27Z
dc.date.available	2025-11-21T05:43:27Z
dc.date.issued	1977
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20158
dc.description	Thermodynamic properties for the solution of hydrogen in palladium and its alloys are experimentally determined under conditions of constant pressure (corresponding to a free surface solid). In this research these data are converted to conditions of constant alloy volume. For palladium/hydrogen it is predicted that the phase change, α→β, which is so characteristic of this system, no longer appears under conditions of constant volume. This is indicative of the fact that long range dipole-dipole elastic interactions predominate in this system. A different sequence of behaviour of ΔµxsH→0 values with atom fraction of substituted metal is predicted for alloys of the type palladium + group IB for constant volume conditions as compared with conditions of constant pressure.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07)	en_US
dc.subject	Chemistry	en_US
dc.subject	Thermodynamic properties	en_US
dc.subject	Palladium	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Thermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volume	en_US
dc.type	Article	en_US