Absolute Rate of the Reaction of C1(2P) with Molecular  Hydrogen from 200-500 K

Lee, Jai H.; Michael, Joe V; Payne, Walter A.; Stiee, Louis J.

dc.contributor.author	Lee, Jai H.
dc.contributor.author	Michael, Joe V
dc.contributor.author	Payne, Walter A.
dc.contributor.author	Stiee, Louis J.
dc.date.accessioned	2025-12-11T10:08:22Z
dc.date.available	2025-12-11T10:08:22Z
dc.date.issued	1977
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/20363
dc.description.abstract	Rate constants for the reaction of atomic chlorine with hydrogen have been measured from 200–500 K using the flash photolysis–resonance fluorescence technique. The rate constants obey the Arrhenius equation k=(2.66 ± 0.42)× 10–11 exp (–2230 ± 60/T) cm3 molecule–1 s–1. The results are compared with previous work and are discussed with particular reference to the equilibrium constant for the reaction and to relative rate data for chlorine atom reactions. Theoretical calculations, using the BEBO method with tunnelling, give excellent agreement with experiment.	en_US
dc.language.iso	en	en_US
dc.publisher	Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10)	en_US
dc.subject	Chemistry	en_US
dc.subject	Molecular hydrogen	en_US
dc.subject	Chemical reaction dynamics	en_US
dc.subject	Journal of the Chemical Society : Faraday Transaction - I	en_US
dc.title	Absolute Rate of the Reaction of C1(2P) with Molecular Hydrogen from 200-500 K	en_US
dc.type	Thesis	en_US