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Synthesis of cobalt-doped bismuth vanadate by combustion-synthesis: Influence of fuel on phase content and morphology

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dc.contributor.author Roy, Banasri
dc.date.accessioned 2021-10-01T11:15:46Z
dc.date.available 2021-10-01T11:15:46Z
dc.date.issued 2011-01-31
dc.identifier.uri https://www.cambridge.org/core/journals/journal-of-materials-research/article/abs/synthesis-of-cobaltdoped-bismuth-vanadate-by-combustionsynthesis-influence-of-fuel-on-phase-content-and-morphology/DAEF65C7AF41D4A1269470C04DA80E41
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2381
dc.description.abstract Cobalt (15 at.%) doped bismuth vanadate, Bi4(V0.85Co0.15)2O11-δ (BICOVOX0.15), is known to have high oxygen ion conduction in the medium temperature range (400–600 °C). Small grain size may be important in stabilizing the highly conductive and disordered γ-phase at lower temperature. In this article, we report for the first time the synthesis of highly porous nanoscale BICOVOX powders by a solution combustion technique. The effects of fuel-to-oxidizer ratio, and postcombustion heat treatment temperature and time on the phase content and microstructure of the powders were investigated. As-combusted powders were revealed to be a mixture of Bi2O3, BiVO4, and γ-BICOVOX phases that were converted to phase pure γ-BICOVOX during heat treatment. en_US
dc.language.iso en en_US
dc.publisher CUP en_US
dc.subject Chemical Engineering en_US
dc.subject Combustion synthesis en_US
dc.subject Ionic conductor en_US
dc.subject Morphology en_US
dc.title Synthesis of cobalt-doped bismuth vanadate by combustion-synthesis: Influence of fuel on phase content and morphology en_US
dc.type Article en_US


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