An elusive vinyl radical isolated as an appended unit in a five-coordinate Co(iii)–bis(iminobenzosemiquinone) complex formed via ligand-centered C–S bond cleavage

dc.contributor.author	Roy, Ram Kinkar
dc.date.accessioned	2021-10-12T11:30:41Z
dc.date.available	2021-10-12T11:30:41Z
dc.date.issued	2016
dc.identifier.uri	https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc02751b
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2718
dc.description.abstract	Redox-active ligand H4Praedt(AP/AP) experienced C–S bond cleavage during complexation reaction with Co(OAc)2·2H2O in the presence of Et3N in CH3OH in air. Thus, formed complex 1 was composed of two iminobenzosemiquinone radicals in its coordination sphere and an unprecedented stable tethered-vinyl radical. The complex has been characterized by mass, X-ray single crystal, X-band EPR, variable-temperature magnetic moment measurements and DFT based computational study.	en_US
dc.language.iso	en	en_US
dc.publisher	RSC	en_US
dc.subject	Chemistry	en_US
dc.subject	Redox-active ligand	en_US
dc.title	An elusive vinyl radical isolated as an appended unit in a five-coordinate Co(iii)–bis(iminobenzosemiquinone) complex formed via ligand-centered C–S bond cleavage	en_US
dc.type	Article	en_US

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