dc.contributor.author | Roy, Ram Kinkar | |
dc.date.accessioned | 2021-10-12T11:30:41Z | |
dc.date.available | 2021-10-12T11:30:41Z | |
dc.date.issued | 2016 | |
dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc02751b | |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2718 | |
dc.description.abstract | Redox-active ligand H4Praedt(AP/AP) experienced C–S bond cleavage during complexation reaction with Co(OAc)2·2H2O in the presence of Et3N in CH3OH in air. Thus, formed complex 1 was composed of two iminobenzosemiquinone radicals in its coordination sphere and an unprecedented stable tethered-vinyl radical. The complex has been characterized by mass, X-ray single crystal, X-band EPR, variable-temperature magnetic moment measurements and DFT based computational study. | en_US |
dc.language.iso | en | en_US |
dc.publisher | RSC | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Redox-active ligand | en_US |
dc.title | An elusive vinyl radical isolated as an appended unit in a five-coordinate Co(iii)–bis(iminobenzosemiquinone) complex formed via ligand-centered C–S bond cleavage | en_US |
dc.type | Article | en_US |
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