| dc.contributor.author |
Roy, Ram Kinkar |
|
| dc.date.accessioned |
2021-10-12T11:32:39Z |
|
| dc.date.available |
2021-10-12T11:32:39Z |
|
| dc.date.issued |
2015 |
|
| dc.identifier.uri |
https://pubs.rsc.org/en/content/articlelanding/2015/DT/C4DT03214D |
|
| dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2725 |
|
| dc.description.abstract |
An azide (–N3) group attached at the -ortho carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol formed a diradical-containing Co(II) complex via inter-ligand azo (N[double bond, length as m-dash]N) bond formation. Metal-to-ligand (azo), dπ-to-pπ* back donation stabilized the metal in its lower oxidation state. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
ACS |
en_US |
| dc.subject |
Chemistry |
en_US |
| dc.subject |
Inter-ligand azo |
en_US |
| dc.title |
Inter-ligand azo (N[double bond, length as m-dash]N) unit formation and stabilization of a Co(ii)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study |
en_US |
| dc.type |
Article |
en_US |