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Synthesis of cupric acetate selective receptor derived from alanyl glycoconjugate and their application in selective oxidation of benzylic alcohols

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dc.contributor.author Sah, Ajay Kumar
dc.date.accessioned 2021-10-14T13:07:57Z
dc.date.available 2021-10-14T13:07:57Z
dc.date.issued 2012-11
dc.identifier.uri https://www.sciencedirect.com/science/article/abs/pii/S1566736712003287?via%3Dihub
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2785
dc.description.abstract Cupric acetate sensing ability of alanyl-(4,6-O-ethylidene-β-D-glucopyranosylamine) derived receptor (L-N2O2) has been explored using fluorescence and UV–visible absorption spectroscopy. Cupric acetate quenches the fluorescence intensity of L-N2O2 with a correlation coefficient, R = 0.978 and Stern Volmer constant, KSV = 38,067 M− 1 revealing the possibilities of interaction via dynamic mode. Further, copper complex of L-N2O2 has been utilized in selective oxidation of primary and secondary alcohols into the corresponding carbonyl compounds. en_US
dc.language.iso en en_US
dc.publisher ACS en_US
dc.subject Chemistry en_US
dc.subject Glucopyranosylamine en_US
dc.subject Copper en_US
dc.subject Fluorescence en_US
dc.title Synthesis of cupric acetate selective receptor derived from alanyl glycoconjugate and their application in selective oxidation of benzylic alcohols en_US
dc.type Article en_US


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