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Design, synthesis and evaluation of carbamoylmethylphosphine sulfide (CMPS)-based chelates for separation of lanthanides and actinides

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dc.contributor.author Sah, Ajay Kumar
dc.date.accessioned 2021-10-14T13:08:05Z
dc.date.available 2021-10-14T13:08:05Z
dc.date.issued 2007-11
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S1631074807000495?via%3Dihub
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2787
dc.description.abstract C3-symmetric triphenoxymethane platforms were substituted with carbamoylmethylphosphine sulfide arms and these tris-CMPS compounds were evaluated as extractants for f-element metal ions from 1 M nitric acid solution. Their properties were compared to the carbamoylmethylphosphine oxide derivatives on the same triphenoxymethane platform (tris-CMPO). The terbium complex of tris-CMPS was crystallized and examined via X-ray structural analysis to provide valuable insight into the binding properties of the soft tripodal chelate. en_US
dc.language.iso en en_US
dc.publisher Elsiever en_US
dc.subject Chemistry en_US
dc.subject Phosphine sulfide ligands en_US
dc.subject f-Element ions separation en_US
dc.subject Nuclear waste separation en_US
dc.title Design, synthesis and evaluation of carbamoylmethylphosphine sulfide (CMPS)-based chelates for separation of lanthanides and actinides en_US
dc.type Article en_US


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