| dc.contributor.author | Kumar, Anil | |
| dc.date.accessioned | 2021-10-14T13:10:07Z | |
| dc.date.available | 2021-10-14T13:10:07Z | |
| dc.date.issued | 2020 | |
| dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2020/cc/d0cc03599h | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2815 | |
| dc.description.abstract | This report describes the synthesis of a new class of secondary interaction (SeCH⋯Cl)-controlled molecular rotor having a Cl–Pd–Cl rotor spoke attached onto a Se–Pd–Se axle. NMR data acquired at various temperatures established ΔG‡298K/ΔG‡350K values of 15.5 and 17.2 kcal mol−1 for a roughly 4.5 Å-long rotor. The molecular rotor showed excellent catalytic activity with reverse regioselectivity for annulation of 2-arylimidazo[1,2-a]pyridines (yields: ∼53–78%) with only 1.5 mol% catalyst loading. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | RSC | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Selenium-coordinated | en_US |
| dc.title | A selenium-coordinated palladium(ii) trans-dichloride molecular rotor as a catalyst for site-selective annulation of 2-arylimidazo[1,2-a]pyridines | en_US |
| dc.type | Article | en_US |
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