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NEXT Access to Substituted Dihydrothiopyrano[2,3-b]indoles via Sequential Rearrangements During S-Alkylation and Au-Catalyzed Hydroarylation on Indoline-2-thiones

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dc.contributor.author Kumar, Anil
dc.date.accessioned 2021-10-17T13:56:47Z
dc.date.available 2021-10-17T13:56:47Z
dc.date.issued 2020-04-20
dc.identifier.uri https://pubs.acs.org/doi/10.1021/jo5025943
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2863
dc.description.abstract An efficient methodology for the synthesis of indole-fused dihydrothiopyrans has been developed from indoline-2-thiones. The protocol involves the synthesis of conjugated ene-yne-substituted indole-sulfides, a gold(III)-catalyzed rearrangement of the ene-yne side chain followed by intramolecular hydroarylation via C3–H functionalization of the indole core. This new synthesis of functionalized tricyclic indole derivatives through sequential rearrangements is quite general in nature en_US
dc.language.iso en en_US
dc.publisher ACS en_US
dc.subject Chemistry en_US
dc.subject Indoles en_US
dc.subject Hydrocarbons en_US
dc.subject Aromatic compounds en_US
dc.title NEXT Access to Substituted Dihydrothiopyrano[2,3-b]indoles via Sequential Rearrangements During S-Alkylation and Au-Catalyzed Hydroarylation on Indoline-2-thiones en_US
dc.type Article en_US


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