dc.contributor.author |
Kumar, Anil |
|
dc.date.accessioned |
2021-10-27T04:10:19Z |
|
dc.date.available |
2021-10-27T04:10:19Z |
|
dc.date.issued |
2011-10-12 |
|
dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S0040403911013323?via%3Dihub |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2929 |
|
dc.description.abstract |
A novel task-specific ionic liquid, 1-butyl-3-methylimidazolium p-toluenesulfinate, [bmim][p-TolSO2] has been synthesized and used as a nucleophile for the reaction with alkyl bromides and phenacyl bromides to prepare sulfones and β-ketosulfones in excellent yields (80–93%) in [bmim][BF4] ionic liquid. The isolated yields of sulfones and β-ketosulfones were higher in [bmim][BF4] than other organic solvents at room temperature. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsiever |
en_US |
dc.subject |
Chemistry |
en_US |
dc.subject |
Ionic liquid |
en_US |
dc.subject |
Task-specific ionic liquid |
en_US |
dc.subject |
β-Ketosulfones |
en_US |
dc.subject |
Nucleophilic substitution |
en_US |
dc.subject |
Phenacyl bromides |
en_US |
dc.title |
1-Butyl-3-methylimidazolium p-toluenesulfinate: a novel reagent for synthesis of sulfones and β-ketosulfones in ionic liquid |
en_US |
dc.type |
Article |
en_US |