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1-Butyl-3-methylimidazolium p-toluenesulfinate: a novel reagent for synthesis of sulfones and β-ketosulfones in ionic liquid

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dc.contributor.author Kumar, Anil
dc.date.accessioned 2021-10-27T04:10:19Z
dc.date.available 2021-10-27T04:10:19Z
dc.date.issued 2011-10-12
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S0040403911013323?via%3Dihub
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/2929
dc.description.abstract A novel task-specific ionic liquid, 1-butyl-3-methylimidazolium p-toluenesulfinate, [bmim][p-TolSO2] has been synthesized and used as a nucleophile for the reaction with alkyl bromides and phenacyl bromides to prepare sulfones and β-ketosulfones in excellent yields (80–93%) in [bmim][BF4] ionic liquid. The isolated yields of sulfones and β-ketosulfones were higher in [bmim][BF4] than other organic solvents at room temperature. en_US
dc.language.iso en en_US
dc.publisher Elsiever en_US
dc.subject Chemistry en_US
dc.subject Ionic liquid en_US
dc.subject Task-specific ionic liquid en_US
dc.subject β-Ketosulfones en_US
dc.subject Nucleophilic substitution en_US
dc.subject Phenacyl bromides en_US
dc.title 1-Butyl-3-methylimidazolium p-toluenesulfinate: a novel reagent for synthesis of sulfones and β-ketosulfones in ionic liquid en_US
dc.type Article en_US


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