| dc.contributor.author | Sarkar, Bibhas R. | |
| dc.date.accessioned | 2021-10-27T04:18:27Z | |
| dc.date.available | 2021-10-27T04:18:27Z | |
| dc.date.issued | 2002 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ja025991q | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3009 | |
| dc.description.abstract | We report here, for the first time, synthesis of anchored Pd complexes in mesoporous supports such as MCM-41 and MCM-48 as true heterogeneous catalysts for hydrocarboxylation of aryl olefins and alcohols to give excellent conversion (∼100%) and regioselectivity (∼99%) for 2-arylpropionic acids. The catalysts were characterized by powder-XRD, 31P CP-MAS NMR, FT-IR, TEM, XPS and ICP-AES. Recycle studies with these anchored Pd mesoporous catalysts were performed to confirm true heterogeneity. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Palladium | en_US |
| dc.subject | Hydrocarbons | en_US |
| dc.subject | Alcohols | en_US |
| dc.subject | Catalysts | en_US |
| dc.subject | Selectivity | en_US |
| dc.title | Anchored Pd Complex in MCM-41 and MCM-48: Novel Heterogeneous Catalysts for Hydrocarboxylation of Aryl Olefins and Alcohols | en_US |
| dc.type | Article | en_US |
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