| dc.contributor.author |
Laskar, Inamur Rahaman |
|
| dc.date.accessioned |
2021-10-27T04:26:21Z |
|
| dc.date.available |
2021-10-27T04:26:21Z |
|
| dc.date.issued |
2004-08 |
|
| dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S1388248104001523?via%3Dihub |
|
| dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3142 |
|
| dc.description.abstract |
Electrogenerated chemiluminescence (ECL) studies have been performed for the iridium(III) cyclometalated L2Ir(acac) complexes with substituted 2-phenylbenzothiazole ligand L. Electron transfer (ET) generation of the excited 3*L2Ir(acac) has been studied using a triple-potential-step technique in acetonitrile–dioxane (1:1) solutions containing 0.1 M (n-C4H9)4NPF6 as the supporting electrolyte. ET reactions between electrochemically generated L2Ir(acac)+ and A− (radical anions of aromatic nitriles) species lead to very efficient generation of ECL emission. Extremely high ECL efficiencies (up to 0.40) close to the excited 3*L2Ir(acac) luminescence yields have been found. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
Elsiever |
en_US |
| dc.subject |
Chemistry |
en_US |
| dc.subject |
Electrogenerated chemiluminescence |
en_US |
| dc.subject |
Iridium complexes |
en_US |
| dc.subject |
MLCT excited state |
en_US |
| dc.title |
Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands |
en_US |
| dc.type |
Article |
en_US |