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A 1D thiocyanato bridge nickel(II) system: crystal structure and magnetic property

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dc.contributor.author Laskar, Inamur Rahaman
dc.date.accessioned 2021-10-27T04:26:39Z
dc.date.available 2021-10-27T04:26:39Z
dc.date.issued 2001-04
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S027753870100729X
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3147
dc.description.abstract A one-dimensional coordination polymer of nickel(II), [(μN,S-NCS)2{Ni(ampy)}]n (ampy=1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300–18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J=1.4 cm−1 and g=2.08. en_US
dc.language.iso en en_US
dc.publisher Elsiever en_US
dc.subject Chemistry en_US
dc.subject Crystal structures en_US
dc.subject Magnetic properties Nickel(II) complexes en_US
dc.subject Thiocyanato bridge complexes en_US
dc.title A 1D thiocyanato bridge nickel(II) system: crystal structure and magnetic property en_US
dc.type Article en_US


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