| dc.contributor.author |
Laskar, Inamur Rahaman |
|
| dc.date.accessioned |
2021-10-27T04:26:44Z |
|
| dc.date.available |
2021-10-27T04:26:44Z |
|
| dc.date.issued |
2000-04-30 |
|
| dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S027753870000365X?via%3Dihub |
|
| dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3149 |
|
| dc.description.abstract |
The complexes [NiL3](NO2)2·2H2O (violet, 1) and cis-[NiL2(NO2)2]·0.5H2O (pink, 1b) (L=1,2-diamino-2-methylpropane) have been synthesized from solution. The X-ray single crystal structure analysis of compound 1b has been carried out, but the presence of a water molecule cannot be detected. Upon heating, complex 1b undergoes dehydration followed by an endothermic phase transition to produce trans-[NiL2(NO2)2] (1d). The violet species (1) also undergoes dehydration upon heating with deamination resulting (1d). |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
Elsiever |
en_US |
| dc.subject |
Chemistry |
en_US |
| dc.subject |
Cis–trans isomerism |
en_US |
| dc.subject |
Crystal structures |
en_US |
| dc.subject |
1,2-Diamino-2-methylpropane |
en_US |
| dc.title |
Cis–trans isomerism in nickel(II)–diamine nitrite: synthesis and single crystal structure of an unusual cis-dinitronickel(II) complex, [NiL2(NO2)2] (L=1,2-diamino-2-methylpropane) |
en_US |
| dc.type |
Article |
en_US |