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A simple route to tetracyclic oxazepine-fused pyrroles via metal-free [3+2] annulation between dibenzo[b,f][1,4]oxazepines and aqueous succinaldehyde

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dc.contributor.author Kumar, Indresh
dc.date.accessioned 2021-10-27T04:27:21Z
dc.date.available 2021-10-27T04:27:21Z
dc.date.issued 2019
dc.identifier.uri https://pubs.rsc.org/en/content/articlelanding/2019/nj/c8nj04861d
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3162
dc.description.abstract A direct method for the synthesis of new tetracyclic oxazepine-fused pyrroles has been developed through [3+2] annulation between aqueous succinaldehyde and dibenzo[b,f][1,4]-oxazepines under metal-free conditions. This one-pot synthetic protocol involves proline-catalyzed direct Mannich/cyclization between aqueous succinaldehyde and seven-membered oxazepine-imines, followed by an IBX-mediated oxidation sequence with high yields (up to 90%). en_US
dc.language.iso en en_US
dc.publisher RSC en_US
dc.subject Chemistry en_US
dc.subject Tetracyclic oxazepine-fused en_US
dc.subject Oxazepines en_US
dc.subject Aqueous succinaldehyde en_US
dc.title A simple route to tetracyclic oxazepine-fused pyrroles via metal-free [3+2] annulation between dibenzo[b,f][1,4]oxazepines and aqueous succinaldehyde en_US
dc.type Article en_US


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