| dc.contributor.author |
Sarkar, Madhushree |
|
| dc.date.accessioned |
2021-11-11T10:42:58Z |
|
| dc.date.available |
2021-11-11T10:42:58Z |
|
| dc.date.issued |
2006 |
|
| dc.identifier.uri |
https://pubs.acs.org/doi/abs/10.1021/cg060216y |
|
| dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3204 |
|
| dc.description.abstract |
Open (4,4)-coordination networks were shown to assemble via N−H···O hydrogen bonds in two different ways: the usual offset packing via β-sheet hydrogen bonds and an unprecedented trigonal packing. Both of the structures have continuous channels that are occupied by guest molecules (nitrobenzene or EtOH and H2O) which account for 37% or 28% of the crystal volume. Interestingly, these complexes have shown an ability to exchange ClO4- with PF6- ions and transform into the doubly interpenetrated varieties. |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
ACS |
en_US |
| dc.subject |
Chemistry |
en_US |
| dc.subject |
Amides |
en_US |
| dc.subject |
Crystal structures |
en_US |
| dc.subject |
Layers |
en_US |
| dc.title |
Interplay of Hydrogen Bonds in Assembling (4,4)-Coordination Networks: Transformations from Open to Interpenetrated Networks via Anion Exchange |
en_US |
| dc.type |
Article |
en_US |