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Facile β-Alkyl and β-Hydride Elimination in the Nickel-Catalyzed Annulation of o-Iodophenyl Ketones and Aldehydes with Bicyclic Alkenes

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dc.contributor.author Shukla, Paritosh
dc.date.accessioned 2021-11-11T10:54:03Z
dc.date.available 2021-11-11T10:54:03Z
dc.date.issued 2006-05-26
dc.identifier.uri https://pubs.acs.org/doi/10.1021/ol061051p
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3291
dc.description.abstract o-Iodoaryl aldehydes react with bicyclic alkenes in the presence of NiBr2(dppe) and Zn powder in acetonitrile at 80 °C undergoing annulation to give polycyclic ketone derivatives. Surprisingly, o-iodoaryl alkyl ketones also react with bicyclic alkenes to form polycyclic ketones with structures the same as those from the corresponding o-iodoaryl aldehydes. en_US
dc.language.iso en en_US
dc.publisher ACS en_US
dc.subject Chemistry en_US
dc.subject Hydrocarbons en_US
dc.subject Annulations en_US
dc.subject Reaction products en_US
dc.title Facile β-Alkyl and β-Hydride Elimination in the Nickel-Catalyzed Annulation of o-Iodophenyl Ketones and Aldehydes with Bicyclic Alkenes en_US
dc.type Article en_US


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