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Reducing-Agent-Free Convergent Synthesis of Hydroxyimino-Decorated Tetracyclic Fused Cinnolines via RhIII-Catalyzed Annulation Using Nitroolefins

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dc.contributor.author Sakhuja, Rajeev
dc.date.accessioned 2021-11-11T10:57:56Z
dc.date.available 2021-11-11T10:57:56Z
dc.date.issued 2021-01
dc.identifier.uri https://pubs.acs.org/doi/10.1021/acs.joc.0c02729
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3342
dc.description.abstract A mild Rh-catalyzed method was developed for the synthesis of hydroxyimino functionalized indazolo[1,2-a]cinnolines and phthalazino[2,3-a]cinnolines by reductive [4 + 2] annulation between 1-arylindazolones and 2-aryl-2,3-dihydrophthalazine-1,4-diones with varied nitroolefins. The targeted oxime decorated tetracyclic fused cinnolines were synthesized via sequential C–H activation/olefin insertion/reduction under reducing-agent-free conditions. en_US
dc.language.iso en en_US
dc.publisher ACS en_US
dc.subject Chemistry en_US
dc.subject Annulations en_US
dc.subject H2 Purification en_US
dc.subject Organic compounds en_US
dc.subject Column chromatography en_US
dc.subject Ethanol en_US
dc.title Reducing-Agent-Free Convergent Synthesis of Hydroxyimino-Decorated Tetracyclic Fused Cinnolines via RhIII-Catalyzed Annulation Using Nitroolefins en_US
dc.type Article en_US


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