| dc.contributor.author | Sakhuja, Rajeev | |
| dc.date.accessioned | 2021-11-11T11:01:58Z | |
| dc.date.available | 2021-11-11T11:01:58Z | |
| dc.date.issued | 2011-04-11 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/jo200088s | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3387 | |
| dc.description.abstract | Carbene-mediated transformations of N-(3-butylbenzimidazol-3-ium-1-yl)-1-arylmethanimine iodides with carbon disulfide and benzoyl isothiocyanate gave the corresponding NHC·CS2 betaines in 68−85% and benzoyl-[1-butyl-3-[(E)-(aryl)methyleneamino]benzimidazol-1-ium-2-carbothioyl]azanides, respectively, in 74−85% yields. However, reaction with excess isopropyl isothiocyanate in NaH/THF at room temperature yielded the 1-butyl-1′,3′-diisopropyl-3-[(E)-(aryl)methyleneamino]spiro[benzimidazole-2,5′-imidazolidine]-2′,4′-dithiones (74−77%). | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Crystals | en_US |
| dc.subject | Adducts | en_US |
| dc.subject | Anions | en_US |
| dc.title | Carbene-Mediated Transformations of 1-(Benzylideneamino)benzimidazoles | en_US |
| dc.type | Article | en_US |
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