dc.contributor.author | Chakraborty, Shamik | |
dc.date.accessioned | 2021-11-11T11:04:34Z | |
dc.date.available | 2021-11-11T11:04:34Z | |
dc.date.issued | 2021-07-16 | |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0009261421003006?via%3Dihub | |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3412 | |
dc.description.abstract | 1-butanol has fourteen distinct conformers. Vibrational spectroscopy in O-H and C-O stretching frequency region is reported earlier. Conformer specific assignment is not yet carried out. Herein, 1-butanol is investigated in the nitrogen matrix at 8 K. Eight distinct bands have been observed in the O-H stretching region and nine distinct bands have been observed in the C-O stretching region. Conformer specific assignment of the observed O-H and C-O bands is carried out. Thermal cyclisation of the deposited matrix resulted isomerisation between the two most stable conformers along with others that has been monitored using O-H and C-O bands. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsiever | en_US |
dc.subject | Chemistry | en_US |
dc.subject | 1-butanol | en_US |
dc.subject | Matrix Isolation | en_US |
dc.subject | Thermal isomerisation | en_US |
dc.subject | Clusters | en_US |
dc.subject | Tunnelling | en_US |
dc.title | A matrix isolation infrared spectroscopic study of thermal isomerisation of 1-butanol | en_US |
dc.type | Article | en_US |
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