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A matrix isolation infrared spectroscopic study of thermal isomerisation of 1-butanol

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dc.contributor.author Chakraborty, Shamik
dc.date.accessioned 2021-11-11T11:04:34Z
dc.date.available 2021-11-11T11:04:34Z
dc.date.issued 2021-07-16
dc.identifier.uri https://www.sciencedirect.com/science/article/pii/S0009261421003006?via%3Dihub
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3412
dc.description.abstract 1-butanol has fourteen distinct conformers. Vibrational spectroscopy in O-H and C-O stretching frequency region is reported earlier. Conformer specific assignment is not yet carried out. Herein, 1-butanol is investigated in the nitrogen matrix at 8 K. Eight distinct bands have been observed in the O-H stretching region and nine distinct bands have been observed in the C-O stretching region. Conformer specific assignment of the observed O-H and C-O bands is carried out. Thermal cyclisation of the deposited matrix resulted isomerisation between the two most stable conformers along with others that has been monitored using O-H and C-O bands. en_US
dc.language.iso en en_US
dc.publisher Elsiever en_US
dc.subject Chemistry en_US
dc.subject 1-butanol en_US
dc.subject Matrix Isolation en_US
dc.subject Thermal isomerisation en_US
dc.subject Clusters en_US
dc.subject Tunnelling en_US
dc.title A matrix isolation infrared spectroscopic study of thermal isomerisation of 1-butanol en_US
dc.type Article en_US


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