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Interfacial charge recombination of Os(ii)–polypyridyl–resorcinol complex on oleic acid capped TiO2 surface: what determines the dynamics?

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dc.contributor.author Banerjee, Tanmay
dc.date.accessioned 2021-11-11T11:22:34Z
dc.date.available 2021-11-11T11:22:34Z
dc.date.issued 2013
dc.identifier.uri https://pubs.rsc.org/en/content/articlelanding/2013/nj/c3nj00550j
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3490
dc.description.abstract Femtosecond transient absorption spectroscopic studies of an osmium(II)–polypyridyl–resorcinol complex, 1, on oleic acid capped TiO2 have been carried out and the results have been compared with our previous studies on poly(vinyl)alcohol capped TiO2. While on both these surfaces the complex exhibits a single exponential <120 fs injection, the back electron transfer reaction is slower on the oleic acid capped TiO2 surface early on while it is faster on the same surface at longer times than on poly(vinyl)alcohol capped TiO2. The probable origin of these disparate observations has been analyzed. en_US
dc.language.iso en en_US
dc.publisher RSC en_US
dc.subject Chemistry en_US
dc.subject Os(ii)–polypyridyl–resorcinol en_US
dc.title Interfacial charge recombination of Os(ii)–polypyridyl–resorcinol complex on oleic acid capped TiO2 surface: what determines the dynamics? en_US
dc.type Article en_US


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