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Now showing items 61-80 of 17872

Redox Reactions between Halides and Reducing Metal Complexes in Non-aqueous Solution: Part 2.—Derivatives of Molybdenum Carbonyl

Bamford, Clement H.; Sakamoto, Izumi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Molybdenum carbonyl undergoes ligand exchange with vinyl monomers such as methyl metha crylate (mma) to produce complexes of the type Mo(CO)5fmma) (I) which readily enter into redox processes with organic halides to ...
Redox Reactions between Halides and Reducing Metal Complexes in Non-aqueous Solution: Part 1.—Derivatives of Tetrakis(triphenyl phosphite)nickel(O)

Bamford, Clement H.; Sakamoto, Izumi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Tetrakisftriphcnyl phosphite)nickel(O) (Ni(tp)4) undergoes ligand exchange with electron donors such as methyl methacrylate (mma) to form complexes of the type Ni(tp)3(mma) which enter into redox reactions with organic ...
Triple Point of the First Monomolecular Layer of Krypton Adsorbed on the Cleavage Face of Graphite: Influence of the Structure of this Surface on the Structure of the First Adsorbed Layer of Rare Gases

Larher, Y. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

From adsorption isotherms of krypton on graphite measured between 79.24 and 88.46 K. in the monolayer domain a two-dimensional triple point of 84.8 ± 0.5 K is determined for this system. Thermodynamic analysis of these ...
Free Radical Addition to Olefins: Part 12.—Addition of Bromodifluoromethyl Radicals to Fluoroethylenes

Tedder, John M.; Walton, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The kinetics of the photochemical addition of dibromodifluororncthanc to vinyl fluoride, 1,1- difluoroethylene and tetrafluoroethylene has been examined in gas phase experiments. The mech anism involves the addition ...
Free Radical Addition to Olefins: Part 11.—Telomerization of Tetrafluoroethylene with Dibromodifluoromethane and Trifluoroiodomethane

Ashton, David S.; Tedder, John M.; Walton, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The telomerization of tetrafluoroethylene in the gas phase by CF2Br2 results in the formation of products of general formula Br[CF2]„Br n = 2-11. When CF3I was used the products were found to be CF3[CF2CF2]„I where n ...
Infra-red Determination of the Isotherm of Hydrogen Adsorption on a Pt/Al2O3 Catalyst

Primet, Michel; Basset, Jean-Marie; Mathieu, Michel-Vital (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Of the various forms of hydrogen adsorbed on platinum only hydrogen weakly and reversibly adsorbed is detected by an infra-red band at 2120 cm-1. The preparation of a well dispersed sample of Pt/ALO? catalyst containing ...
Nuclear Spin-lattice Relaxation Times of Alkali Metal Counterions at Micellar Interfaces

Robb, Ian D.; Smith, Royston (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Spin lattice relaxation rates of Li+, Na+, Rb+ and Cs+ have been measured by pulsed n.m.r. in both simple electrolyte solutions and solutions containing surfactant micelles. Relaxation rates for the ions adsorbed at ...
Effect of Hydrostatic Pressure on the Electrical Conductivity of Ag3SBr and £-Ag3SI

Hoshino, H.; Yanagiya, H.; Shimoji, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The electrical conductivity of Ag3SBr and £-Ag3SI has been measured as a function of hydro static pressure up to 3.15xlOsNm-2 in the temperature range 293 to 373 K. The activation volumes obtained at 303 K are —1.2±0.6 ...
Electrical Properties of Molten T12S

Nakamura, Y.; Matsumura, K.; Shimoji, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The electrical conductivity and thermoelectric power of T12S have been measured as a'function of temperature. Non-stoichiometric and impurity doping effects have been investigated. The results for molten T12S containing ...
Electron Spin Resonance Studies of Isotopically Labelled Oxygen Species Adsorbed on Supported Molybdenum

Che, Michel; Tench, Anthony J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The molecular ion (O2)5 has been observed on the surface of the moIybdenum/SiO2 and molyb- denum/Al2O3 systems by e.s.r. Using oxygen isotopically enriched in 17O, two different hyperfine splittings were observed in ...
Proton and Deuteron Mobility in Normal and Heavy Water Solutions of Electrolytes

Roberts, Noel K.; Northey, Helen L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Proton and deuteron mobility in normal and heavy water solutions of some alkali halides (NaCl, KCI, KBr and KI) and tetra-alkylammonium bromides (where alkyl is Me, Et, Pr or Bu) is measured polarographically and the ...
Kinetics of the Thermal Isomerisation of Hexamethyldisilane

Davidson, Iain M. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and 780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on the thermolysis of ...
Ellipsometric Investigation of Black Soap Films

Engelsen, Daan Den; Frens, Gerrit (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Thin soap films of sodium dodecyl sulphate and sodium dodecyl bcnzenesulphonatc have been studied with a combination of ellipsometry and reflectometry. It is demonstrated that an optical three-layer model is superior ...
Intermediates in the Nanosecond Pulse Radiolysis of Triphenylamine Solutions in Cyclohexane

Zador, Erika; Warman, John M.; Luthjens, Leonard H.; Hummel, Andries (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The pulse radiolysis of solutions of triphenylamine (TPA) in cyclohexane has been investigated using nanosecond time resolution. In addition to the transient absorption at 620 nm which has been previously observed in ...
Kinetics of Electrode Reactions in Liquid Ammonia: Part 2.—FeIII/FeII and CoIII/CoII Redox Couples

Brown, Oliver R.; Thornton, Sean A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Polarisation data has been obtained for the CoH/CoHI and Fe'VFc111 couples at rotating disc electrodes of platinum, gold and vitreous carbon at -30°C in ammonia acid solution. In addition, metal wires and carbon rod ...
Hydrogenation of Ethylene on Metal Electrodes: Part 2.—Structure of the Adsorption Layer on Platinum at a Working Condition on Open Circuit

Fujikawa, Keikichi; Katayama, Akiko; Kita, Hideaki (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The structure of the adsorption layer was studied by the potential sweep method on a platinum electrode in 1 N HC104 solution saturated with a reaction gas of various compositions (mixtures of H2, C2H4 and He). Results ...
Tunable energy-efficient approximatunable energy-efficient approximate circuits for self-powered ai and autonomous edge computing systemste circuits for self-powered ai and autonomous edge computing systems

Chaturvedi, Nitin (IEEE, 2025-03)

Artificial Intelligence is applied in various domains of compute-intensive applications ranging from image recognition healthcare to statistical analysis. Additionally, recent advancements in Deep Neural Network (DNN) ...
Efficient edge AI implementation for IoT device identification for hierarchical federated learning

Shenoy, Meetha V. (Inder Science, 2025-03)

As IoT devices proliferate, efficient IoT device identification is crucial for resource management, planning, and detecting anomalous traffic. Traditional ML-based identification relies on centralised training, but federated ...
Deep q-learning framework based solar energy generation prediction

Gupta, Karunesh Kumar (2022)

In the recent years, the power system market has seen a huge shift towards the utilisation of Renewable energy sources (RES) as candidates of power generation since they proved to be a great alternative of conventional ...
A detailed comparative analysis of automatic neural metrics for machine translation: bleurt & bertscore

Chamola, Vinay; Gupta, Karunesh Kumar (IEEE, 2025-04)

Bleurt a recently introduced metric that employs Bert, a potent pre-trained language model to assess how well candidate translations compare to a reference translation in the context of machine translation outputs. While ...

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