Browsing by Author "Abbott, Geoffrey D"
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Item Vapour-phase Exciplex Formation between 1,4-Dicyanonaphthalene and 2,5-Dimethyl-2,4-hexadiene(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981) Abbott, Geoffrey D; O’CoNNOR, Desmond V; Phillips, DavidFluorescence has been observed from the exciplex formed between electronically excited 1,4-dicyanonaphthalene and 2,5-dimethyl-2,4-hexadiene in the vapour phase and the kinetics of exciplex formation studied. The enthalphy of vapour-phase exciplex formation in this pair of molecules was found to be 8 kJ mol–1 and activation energies for formation and reverse dissociation of the exciplex were found to be 15 and 23 kJ mol–1, respectively.