Browsing by Author "Agnew, Andrew"

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Transport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 5.—Irreversible Thermodynamic Parameters for Zinc Perchlorate and Verification of Onsager’s Reciprocal Relationships
(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Agnew, Andrew; Paterson, Russell
The isothermal vectorial transport properties of zinc perchlorate have been measured over the concentration range 0.1–3.0 mol dm–3 at 298.15 K. Hittorf transport numbers were shown to agree with those measured earlier using concentration cells. Conductance and salt diffusion coefficients were also measured. These data were used to calculate mobility (Lik) and resistance (Rik) coefficients using irreversible thermodynamic theory. Analysis showed that the Onsager reciprocal relationships (O.R.R.) were obeyed.
Transport in aqueous solutions of group IIB metal salts at 298.15 K. Part 6.—Irreversible thermodynamic parameters for zinc chloride and verification of Onsager's reciprocal relationships
(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Agnew, Andrew; Paterson, Russell
The isothermal vectorial transport properties of zinc chloride (conductance, transport number and salt diffusion coefficients) have been measured over the concentration range 0.1–3.5 mol dm–3 at 298.15 K. These data have been used to calculate mobility (Lik) and resistance (Rik) coefficients, using irreversible thermodynamic theory. Hittorf and concentration cell estimates of transport number have been used to verify the Onsager reciprocal relationships. The effects of self complexing in zinc chloride are illustrated by comparison with zinc perchlorate and other group IIB metal halides for which data are available.