Browsing by Author "Bannard, John E."
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Item p-V-T Studies on Molten Alkali Nitrates: Part 1.—Thermal Pressure Coefficients and Compressibilities(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (1), 1978) Bannard, John E.; Barton, Allan F. M.The p-V-T relationships of the molten alkali nitrates (Li, Na, K, Rb and Cs) were determined using a gas-pressurised, externally-heated pressure vessel. The cells were the pyknometer type with a long capillary barrier between the pressurising gas and the bulk of the liquid. Data, over a range of temperature from 500 to 800 K and a range of pressure to 1400 bar, were plotted in the form of isochores and used to determine densities and compressibilities of the liquids.Item p-V-T Studies on Molten Alkali Nitrates: Part 2.—Internal Energies and Equation of State(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (1), 1978) Bannard, John E.p-V-T data for the molten alkali nitrates to a temperature of 800 K and a pressure of 1400 bar were used to derive internal pressures and specific heats, and to derive the parameters of the van der Waals equation.