Browsing by Author "Finch, Arthur"

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Appearance and Ionization Potentials of Ions produced by Electron-impact on some Phosphorus-Fluorine Compounds: the Phosphorus-Phosphorus Bond Dissociation Energy in Diphosphorus Tetralluoride
(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974) Dean, Christopher R. S.; Finch, Arthur; Gardner, Peter J.; Payling, David W.
The ionization potentials of P2F4, PF3 PF2H and PF2I and the appearance potentials of the PF+2 ion from these species are reported. The ionization potential of the PF2˙ radical is estimated using approximations for the PF2—X (X = F, I and H) bond dissociation energies. The P—P bond dissociation energy in diphosphorus tetrafluoride is estimated as 57 ± 10 kcal mol–1.