Browsing by Author "Garcia-Dominguez, Jose A"

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    Slow Gas-Phase Oxidation of Ethylal with C-14 as a Tracer
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977) Molera, Maria J; Garcia-Dominguez, Jose A; Lopez, Alvaro Rodriguez; Santiuste, Jose M
    The slow gas-phase oxidation of ethylal was investigated at low temperatures (160–190°C) by the static method. The main products were carbon oxides, water, acetaldehyde, acetic acid, ethanol and ethyl formate with some methanol, formaldehyde, formic acid, n-butane, ethylene and peroxides. Three different ethylal samples labelled with C-14 in each one of its three different positions, respectively, have been synthesized; their oxidation has been studied and the reaction products analysed by radiochromatography. A mechanism is suggested where the branching intermediates are hydroperoxides derived from ethylal.