Browsing by Author "Giuffre, Luigi"

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    Nature of Solutions of Water in Sulphuric Acid
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Sioli, Giancarlo; Giuffre, Luigi; Spaziante, Placido Maria
    Proton magnetic resonance measurements have been used to justify a proposed mechanism for the interaction of water with sulphuric acid, where the molar fraction of water is y⩽ 0.5. Three different statistical states of the proton are considered, expressed by the formulae H3O+, H3O+·HSO–4 and H3O+(H2SO4). The molarities of these species are given for the stated water concentration range.