Browsing by Author "Godfrey, Peter"

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    Kinetics of the reaction of the nickel(II) ion with pyridine-2-azo-p-dimethylaniline in t-butanol + water mixtures
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974) Caldin, Edward F.; Godfrey, Peter
    Rate constants and activation parameters have been determined for the reaction of the nickel(II) ion with pyridine -2-azo-p-dimethylaniline, in a series of t-butanol + water mixtures with mole fractions from 0 to 0.4 t-butanol. The rate constant at 25°C varies little with composition, but the enthalpy and entropy of activation both vary considerably, with compensation; they show maxima and minima, which are discussed in relation to theories of solvent structure.