Browsing by Author "Infante, Gabriel A."

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    Radiolysis of Pyrimidines in Aqueous Solutions: Part 2.—Product Formation in the Interaction of ea~, -H, -OH and C17- with
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974) Infante, Gabriel A.; Jirathana, Poonsri; Fendler, Eleanor J.; Fendler, Janos H.
    Product yields in the reaction of e~, -H, -OH and Cl/ with uracil and uracil- have been determined quantitatively in 60Co y-irradiated aqueous uracil solutions in the presence of suitable scavengers. Good material balances between G(—uracil) and G(total products) have been obtained in all cases. The products determined were: uracil dimer, alloxan, alloxantin, uracil czj-glycol, uracil /ra/u-glycol, dialuric acid, isobarbituric acid, 5-hydroxydihydrouraciI, 6-hydroxydihydrouraciI, dihydrouracil, formylurea, 5-hydroxyhydantoin, parabanic acid, urea and alcohol adducts. Based on the yields of these products and the available literature, mechanisms are proposed and discussed.