Browsing by Author "Martin, John F."
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Item Thermodynamic Properties of Fluorine Compounds: Part 12.Low-temperature Heat Capacity and Entropy of 1,3,5-Trichloro-2,4,6-trifluorobenzene(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973) Andon, Richard J. L.; Martin, John F.The heat capacity of 1,3,5-trichloro-2,4,6-trifluorobenzene was measured by adiabatic calorimetry from 14 to 347 K, and thermodynamic functions were calculated from the results. The heat capacity curve exhibited an anomalous region between 285 and 305 K. The triple point temperature was measured as 335.01 K and the entropy of the crystals at 298.15 K was found to be 243.3 J K–1 mol–1.Item Thermodynamic properties of fluorine compounds: Part 14.—Low-temperature heat capacity and entropy of octafluorotolune(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974) Andon, Richard J. L.; Martin, John F.The heat capacity between 10 and 365 K, the enthalpy of fusion, and the triple-point temperature of octafluorotoluene have been measured. The standard entropy of the ideal gas has been obtained from the results of the measurements and other data.