Browsing by Author "Meyerstein, Dan"

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Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems
(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977) Freiberg, Mira; Meyerstein, Dan
The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+aq and Ni+aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed.
Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems
(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977) Freiberg, Mira; Meyerstein, Dan
The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+aq and Ni+aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed.