Browsing by Author "Parfitt, G D"

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    Infra-red Study of the Surface Properties of Rutile: Adsorption of Ethanol, n-Butanol and n-Hexanol
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972) Jackson, P; Parfitt, G D
    The vapours of ethanol, n-butanol and n-hexanol chemisorb at room temperature on a variety of rutile surfaces. The adsorption is independent of the nature of the surface, and an estimate of the ethoxide population is 3 groups/nm2. Thermal decomposition of all three alkoxides was complete at 300°C producing surface carbonate species, with water and the respective alk-1-ene in the gas phase. A mechanism is proposed for the formation of the alk-1-ene.