Browsing by Author "Shirts, Randall B."

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    Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Hexafluorobenzene with Nitrogen Containing Compounds
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974) Ott, J. Bevan; Goates, J. Rex; Reeder, Joan; Shirts, Randall B.
    Thermal methods have been used to determine with high precision the solid/liqnid phase equilibria diagrams tor mixtures of hcxafluorobcnzene with Y-methylmorpholine, TV-methyipipcridinc and AW'-dimcthylpiperazine. Solid addition compounds form in all three systems. Exploratory measurements show that hcxafluorobcnzene docs not form solid addition compounds with triethyl amine, acetonitrile or AW-dimcthylacetamide. A comparison of the phase diagrams for a number of systems containing hcxafluorobcnzene suggests that compound formation with hcxafluorobcnzene results from a combination of favorable packing geometry and electrostatic interactions.