Browsing by Author "Skelhorne, Graham G."

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    Analysis of Pressure Changes for Simultaneous First-order Decomposition Reactions in a Gas-kinetic System with Dead-space
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Robinson, Peter J.; Skelhorne, Graham G.
    Methods are described for treating the problem of unreactive dead-space when extracting kinetic parameters from total pressure measurements on simultaneous first-order decomposition reactions in a constant-volume gas kinetic system (A → C + D; B → C′+ D′). The proposed methods are verified by applying them to computer-generated “experimental” pressure against time data for systems with a wide range of parameter combinations.