Browsing by Author "Smith, A."
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Item Energy Partition in the Photolysis of HI and of H2S(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (12), 1972) Oldershaw, G. A.; Porter, D. A.; Smith, A.Yields of nitrogen from reaction (1) were used to determine the initial kinetic energy of hydrogen atoms produced by photolysis of HI and H2S in the presence of N2O. H* + N2O->N2 + OH. (1) The results show that the proportion of excited (52P±) iodine atoms formed by photolysis of HI at 279 nm is 0.11 ±0.14, and that 90±10 % of the residual energy following photolysis of H2S at 248 nm appears in translation of H and SH.