Browsing by Author "Tedder, J. M."
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Item Free Radical Addition to Olefins: Part 8.—Addition of of n-Heptafluoropropyl Radicals to Fluoro-ethylenes(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972) Tedder, J. M.; Walton, J. C.; Winton, K. D. R.The light-induced addition of perfluoropropyl iodide to fluoro-ethylenes in the gas phase C3F7·+ RCH[double bond, length as m-dash]CH2→ C3F7CH2ĊHR (2) has been studied, and activation parameters determined by a competitive method. The corresponding differences found are: [graphic omitted] The most striking feature is the similarity to the results for addition of bromotrichloromethane to the same olefins. Relationships between activation energies and some theoretical quantities are discussed.Item Free Radical Addition to Olefins: Part 9. Addition of Methyl Radicals to Fluoro-ethylenes(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972) Tedder, J. M.; Walton, J. C.; Winton, K. D. R.