Browsing by Author "Thrush, Brian A"

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    Reaction of Oxygen Atoms with Nitromethane and with Nitroethane
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977) Salter, Leo F; Thrush, Brian A
    The reaction of oxygen atoms with nitromethane and nitroethane has been studied in a discharge flow system at temperatures between 294 and 473 K. The initial attack involves abstraction of a hydrogen atom, for which the rate expressions are shown to be 10(10.18 ± 0.27) exp (–22.4 ± 1.8 kJ mol–1)/RT dm3 mol–1 s–1 and 10(10.50 ± 0.96) exp (–22.7 ± 7.0 kJ mol–1)/RT dm3 mol–1 s–1 respectively.