Browsing by Author "Trotman-Dickenson, Aubrey F."

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    Reactions of Alkyl Radicals with Nitrogen Trifluoride
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Cadman, Philip; Inel, Yuksel; Trotman-Dickenson, Aubrey F.
    Photolysis of mixtures of nitrogen trifluoride with the appropriate ketones (in the temperature range 303–486 K) has enabled the reactions of CH3, CF3, C2H5, i-C3H7 and t-C4H9 radicals with nitrogen trifluoride to be studied. With the smaller radicals only the abstraction of difluoroamino radicals is important, but with i-C3H7 and t-butyl both difluoroamino and fluorine abstraction occur. The Arrhenius parameters are given. The disproportionation—combination ratio for methyl and t-butyl radicals was found to be 0.83 ± 0.02.