Browsing by Author "Waddington, David J."

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    Self-reactions of Isopropylperoxy Radicals in the Gas Phase
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978) Kirsch, Leslie J.; Parkes, David A.; Waddington, David J.; Woolley, Allan
    The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± 0.03 and Eobs= 18.65 ± 0.50 kJ mol–1 have been determined over a temperature range 300–373 K. These values are compared with those obtained for the self-reactions of primary and tertiary alkylperoxyradicals, and the corresponding reactions in solution.