Journal Articles (before-1995)

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Author: search.filters.author.Tseung, Alfred C. C.Subject: search.filters.subject.Carbon monoxide

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    Catalyst participation in the reduction of sulphur dioxide by carbon monoxide in the presence of water and oxygen
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (08), 1978) Hibbert, D. Brynn; Tseung, Alfred C. C.
    Copper supported on alumina is a catalyst for the reduction of sulphur dioxide by carbon monoxide. In the presence of water and oxygen, calculation of the equilibrium state of the gas phase and condensed phase by a free energy minimisation method reveals that for certain combinations of gas composition and temperature, copper(II) sulphide will be formed. Copper was converted to copper sulphide when used as a catalyst for the reduction of a stoichiometric mixture of sulphur dioxide and carbon monoxide containing 2.4 % water at 580°C. Oxygen is a poison for the reaction.