Journal Articles (before-1995)

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    Complex-formation between Carbon Tetrachloride and Alkyl-substituted Benzenes
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973) Ahmed, Akhlaq
    Measurements of the enthalpies of mixing are presented for equimolar mixtures of carbon tetrachloride with ethylbenzene, cumene, and t-butylbenzene at temperature between 288.00 and 352.96 K. Enthalpies of mixing are also presented for carbon tetrachloride and ethylbenzene over a wide range of composition at 337.97 K at which point the enthalpy of mixing changes sign for an equimolar mixture. A double maximum is obtained in the curve of enthalpy of mixing against the mole fraction of carbon tetrachloride. The results are understood in terms of a simple theory of complex-formation.