Journal Articles (before-1995)
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Item Effect of Hydrostatic Pressure on the Electrical Conductivity of Ag2HgI4 and Cu2HgI4(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974) Shibata, Shuichi; Hoshino, Hideoki; Shimoji, MitsuoThe electrical conductivity of the a and ft phases of Ag2HgI4 and Cu2HgI4 has been measured as a function of hydrostatic pressure up to 3xlO8Nm~2 in the temperature range between 283 and 363 K. The activation volumes determined from the data are temperature-dependent. The results are discussed on the basis of the continuum model for the atomic transport process.Item Effect of Hydrostatic Pressure on the Electrical Conductivity of Ag3SBr and £-Ag3SI(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974) Hoshino, H.; Yanagiya, H.; Shimoji, M.The electrical conductivity of Ag3SBr and £-Ag3SI has been measured as a function of hydro static pressure up to 3.15xlOsNm-2 in the temperature range 293 to 373 K. The activation volumes obtained at 303 K are —1.2±0.6 cm3 mol-1 for Ag3SBr and — 2.3±0.4cm3 mol-1 for /?-Ag3SI. For Ag3SBr the activation volume becomes more positive as temperature rises whereas for /3-Ag3SI it becomes more negative with increasing temperature.