Department of Chemical Engineering

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End date: 2019Subject: search.filters.subject.Biomass

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Now showing 1 - 10 of 11
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    Investigating effects of temperature on fuel properties of torrefied biomass for bio-energy systems
    (Taylor & Francis, 2018-11) Pande, Jay
    Torrefaction of selected agro-residues (rice straw and cotton stalk) was successfully carried out on indirectly heated, batch-type fixed-bed reactor under different reactor temperatures (200–300°C) at a fixed heating rate of 10°C/min. Our preliminary results demonstrated that the rice straw, torrefied at 275°C, exhibited higher mass yield (64%) and energy yield (84%) with better fuel properties, i.e. lower moisture content (1.2%), volatile matters (54.7%), higher fixed carbon (24.8%), and higher heating value (HHV) 18.7 MJ/kg. On the other hand, cotton stalk showed a slightly lower mass yield (56.3%) and energy yield (74.4%) compared to rice star with very high HHV 22.5 MJ/kg torrefied at a relatively lower temperature of 250°C. Interestingly, the lignocellulosic composition showed a drastic increase in the lignin content of rice straw and cotton stalk, torrefied at 275°C and 250°C, respectively, which indicates good binding ability of bio-fuel leading to improved energy density. Our present work gives an insight that the torrefied rice straw and cotton stalk could be a promising biomass feedstock for bio-energy based systems such as biomass pyrolsyis and gasification.
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    Improving the properties of producer gas using high temperature gasification of rice husk in a pilot scale fluidized bed gasifier (FBG)
    (Elsevier, 2019-01) Pandey, Jay
    Biomass gasification is a well-studied thermo-chemical conversion route for the generating producer gas, a renewable energy carrier, for thermal and power applications as well as for bio-fuel production. High energy efficiency and clean gaseous fuel with low tar and suspended particulate matters (SPM) contents are some of the major challenges with biomass gasification. Herein, we report non-catalytic high temperature (720–855 °C) gasification of rice husk using fluidized bed gasifier (FBG). Producer gas mainly comprising of CO and H2 exhibited good higher heating value (HHV) and lower heating value (LHV) of 3.6 and 3.2 MJ/Nm3 respectively. Our experimental observations revealed that 790 °C is the optimum temperature for rice husk gasification with high carbon conversion efficiency (91.6%), thermal efficiency (75%) and high gas yield 2.7 m3/kg. High temperature gasification also resulted into reduced tar + SPM content (0.33 g/Nm3). Rice husk derived producer gas with good heating value and low tar + SPM content can be used as replacement of conventional fossil fuels for thermal applications in many processing industries.
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    A mechanistic study on the reaction pathways leading to benzene and naphthalene in cellulose vapor phase cracking
    (Elsiever, 2014-10) Srinivas, Appari
    The reaction pathways leading to aromatic hydrocarbons such as benzene and naphthalene in gas-phase reactions of multi-component mixtures derived from cellulose fast pyrolysis were studied both experimentally and numerically. A two-stage tubular reactor was used for evaluating the reaction kinetics of secondary vapor phase cracking of the nascent pyrolysates at temperature ranging from 400 to 900 °C, residence time from 0.2 to 4.3 s, and at 241 kPa. The products of alkyne and diene were identified from the primary pyrolysis of cellulose even at low temperature range 500–600 °C. These products include acetylene, propyne, propadiene, vinylacetylene, and cyclopentadiene. Experiments were also numerically validated by a detailed chemical kinetic model consisting of more than 8000 elementary step-like reactions with over 500 chemical species. Acceptable capabilities of the kinetic model in predicting concentration profiles of the products enabled us to assess reaction pathways leading to benzene and naphthalene via the alkyne and diene from primary pyrolysates of cellulose. C3 alkyne and diene are primary precursors of benzene at 650 °C, while combination of ethylene and vinylacetylene produces benzene dominantly at 850 °C. Cyclopentadiene is a prominent precursor of naphthalene. Combination of acetylene with propyne or allyl radical leads to the formation of cyclopentadiene. Furan and acrolein are likely important alkyne precursors in cellulose pyrolysis at low temperature, whereas dehydrogenations of olefins are major route to alkyne at high temperatures.
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    Advances in Downdraft Biomass Gasification
    (‎ Nova Science Publishers, 2010) Sheth, P.N.
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    Differential Evolution Approach for Obtaining Kinetic Parameters in Nonisothermal Pyrolysis of Biomass
    (Taylor & Francis, 2009-05) Sheth, P.N.
    Pyrolysis, a first step in the biomass gasification, is the thermal decomposition of organic matter under inert atmospheric conditions, leading to the release of volatiles and formation of char. As pyrolysis is a kinetically controlled reaction, kinetic parameter estimation is very important in the design of pyrolysis reactors. In the proposed kinetic model of this study, the kinetic scheme of biomass decomposition by two competing reactions giving gaseous volatiles and solid charcoal is used. Four different models are proposed based on different possible relation of activity of biomass with normalized conversion. The corresponding kinetic parameters of the above models are estimated by minimizing the square of the error between the reported nonisothermal experimental data of thermogravimetry of hazelnut shell and simulated model predicted values of residual weight fraction using differential evolution (DE), a population-based search algorithm. Among the four different models proposed in this study, the model in which rate of change of activity of biomass with normalized conversion proposed as a function of activity itself gave the best agreement with the experimental data.
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    Experimental studies on producer gas generation from wood waste in a downdraft biomass gasifier
    (Elsiever, 2009-06) Sheth, P.N.
    A process of conversion of solid carbonaceous fuel into combustible gas by partial combustion is known as gasification. The resulting gas, known as producer gas, is more versatile in its use than the original solid biomass. In the present study, a downdraft biomass gasifier is used to carry out the gasification experiments with the waste generated while making furniture in the carpentry section of the institute’s workshop. Dalbergia sisoo, generally known as sesame wood or rose wood is mainly used in the furniture and wastage of the same is used as a biomass material in the present gasification studies. The effects of air flow rate and moisture content on biomass consumption rate and quality of the producer gas generated are studied by performing experiments. The performance of the biomass gasifier system is evaluated in terms of equivalence ratio, producer gas composition, calorific value of the producer gas, gas production rate, zone temperatures and cold gas efficiency. Material balance is carried out to examine the reliability of the results generated. The experimental results are compared with those reported in the literature.
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    Thermo-Chemical Conversion of Jatropha Deoiled Cake: Pyrolysis vs. Gasification
    (IJCEA, 2015-10) Sheth, P.N.
    Pyrolysis and gasification of biomass is considered to be the promising alternative solutions for the increase of energy demand and environmental awareness. Pyroysis process produces a variety of chemicals by limited degradation and gasification process leads to complete breakdown of the biomass into permanent gases. By gasification, solid biomass is converted into a combustible gas mixture normally called “Producer Gas” consisting primarily of hydrogen and carbon monoxide, with lesser amounts of carbon dioxide, water, methane, higher hydrocarbons, nitrogen and particulates. Whereas the pyrolysis process produces a mainly three types of products: solid (charcoal), liquid (tar and other organics) and gaseous products. In the present study, Jatropha de-oiled cake is taken as a biomass. The pyrolysis and gasification experiments are carried out for comparing the results. The biomass is pyrolyzed in a fixed bed reactor in a Nitrogen environment as well used to produce the producer gas in a fixed bed downdraft biomass gasifier.
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    Biomass gasification models for downdraft gasifier: A state-of-the-art review
    (Elsiever, 2015-10) Sheth, P.N.
    Among the different methods of energy production from biomass, gasification is considered as the most suitable option as it is a simple and economically viable process to produce thermal energy or decentralized electricity generation. Downdraft gasifiers are typically small-scale units having maximum power production capacity up to 5 MW. This feature makes it more suitable for decentralized power generation and distribution to the remote villages/islands deprived of grid electricity. Mathematical models can be helpful for the design of gasifiers, prediction of operational behavior, emissions during normal conditions, startup, shutdown, change of fuel, change of loading, and to alleviate the type of problems mentioned above. It has been observed that although many researchers have developed models of various types and degrees of complexity, reviews of these modeling and simulation studies are scarce. Largely, it is observed that the review articles reported in the literature fail to address the basic understanding of each model types and their applicability to design different gasifiers for a certain feedstock and variation of operating parameters. This review article discusses different models available for downdraft gasifiers such as thermodynamic equilibrium, kinetic, CFD, ANN and ASPEN Plus models. A comparative analysis of each model and its output is carried out. A critical analysis of the effect of different modeling parameters and finally the advantages and disadvantages of each modeling technique is outlined.
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    Design of energy utilization test for a biomass cook stove: Formulation of an optimum air flow recipe
    (Elsiever, 2019-01-01) Sheth, P.N.
    Biomass is a major source of fuel in many developing countries and used in cook stoves. The water boiling test or its variants are used to evaluate the performance. The evaluation is on an average basis throughout the test and does not provide the dynamics of the energy transfer process. To provide a better insight on this transfer process, the present study demonstrates energy utilization test, which enables analysis of the performance parameters with respect to time. The WBT experimental set up is modified to measure the variation of biomass fuel consumption and water evaporation separately with time by incorporating the separate top mounted weighing balance. The new variable, weight of the water pot, variation with time is also observed along with other standard WBT variables. This new test is validated by performing several experiments. It provides insights on the time-dependent behavior of thermal efficiency and other parameters when performed at different air flow rates. Based on the test results, a new air flow recipe is developed which provides better performance and outlines the significance of energy utilization test. With the formulated recipe, the runtime has improved to nearly 85 min which is an increase of more than 30%.