Journal Archive Collections
Permanent URI for this communityhttp://localhost:4000/handle/123456789/16937
Browse
1 results
Search Results
Item Appearance and Ionization Potentials of Ions produced by Electron-impact on some Phosphorus-Fluorine Compounds: the Phosphorus-Phosphorus Bond Dissociation Energy in Diphosphorus Tetralluoride(Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974) Dean, Christopher R. S.; Finch, Arthur; Gardner, Peter J.; Payling, David W.The ionization potentials of P2F4, PF3 PF2H and PF2I and the appearance potentials of the PF+2 ion from these species are reported. The ionization potential of the PF2˙ radical is estimated using approximations for the PF2—X (X = F, I and H) bond dissociation energies. The P—P bond dissociation energy in diphosphorus tetrafluoride is estimated as 57 ± 10 kcal mol–1.