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Subject: search.filters.subject.Benzene

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    Radiolysis of Benzene+Bromobenzene Solutions
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973) Kumar, S. S.; Merklin, J. F.
    Yields of γ-ray radiolysis products from benzene, bromobenzene and solutions of benzene and bromobenzene have been measured. The yield of biphenyl was larger in the solutions than in either of the pure solvents. Rate constants for quenching reactions were estimated on the basis of the measured product spectra and the published value of the ratio of rate constants for quenching in benzene +p-terphenyl + bromobenzene solutions.
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    Pressure and Temperature Dependence of the Self-diffusion of Benzene
    (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972) McCool, M A; Collings, A F; Woolf, L A
    The self-diffusion coefficient of liquid benzene has been measured with a modified diaphragm cell. The cell incorporates a bellows in one compartment and the technique for its use makes allowance for bulk flow effects due to changes in pressure. Results have been obtained at 288, 298, 313 and 328 K over the pressure ranges 1-283, 1-645, 1-975 and 1-1496 bar, respectively and used to calculate activation energies and volumes. In contrast to earlier (less accurate) data the present results indicate a non-linear dependence of log D on pressure. The results are used to test a quasi-lattice model of the liquid. The Stokes-Einstein relation is obeyed over only a narrow density range.