Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands
| dc.contributor.author | Laskar, Inamur Rahaman | |
| dc.date.accessioned | 2021-10-27T04:26:21Z | |
| dc.date.available | 2021-10-27T04:26:21Z | |
| dc.date.issued | 2004-08 | |
| dc.description.abstract | Electrogenerated chemiluminescence (ECL) studies have been performed for the iridium(III) cyclometalated L2Ir(acac) complexes with substituted 2-phenylbenzothiazole ligand L. Electron transfer (ET) generation of the excited 3*L2Ir(acac) has been studied using a triple-potential-step technique in acetonitrile–dioxane (1:1) solutions containing 0.1 M (n-C4H9)4NPF6 as the supporting electrolyte. ET reactions between electrochemically generated L2Ir(acac)+ and A− (radical anions of aromatic nitriles) species lead to very efficient generation of ECL emission. Extremely high ECL efficiencies (up to 0.40) close to the excited 3*L2Ir(acac) luminescence yields have been found. | en_US |
| dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S1388248104001523?via%3Dihub | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3142 | |
| dc.language.iso | en | en_US |
| dc.publisher | Elsiever | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Electrogenerated chemiluminescence | en_US |
| dc.subject | Iridium complexes | en_US |
| dc.subject | MLCT excited state | en_US |
| dc.title | Electrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligands | en_US |
| dc.type | Article | en_US |
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